Episode 2 was Brilliant! (no spoilers)
I didn't like the first episode because it reminded me too much of Friends. No sin here, because all sitcoms are and will be compared with either Friends or Seinfeld.
However, after watching the second episode I must say that I see the show's real potential, and I look forward to watching the upcoming episodes. Now I start to understand each character's personality, some of which of course remind me of Chandler and Phoebe.
Episode 2 was so funny, that I can't help wondering why it wasn't choosen as the first episode of the show. First impressions count, everybody knows that.
So I say: let's give 100 Questions a chance. It started very poorly with a weak pilot, but let's not forget that Friend's pilot was awful.