That's an easy question to answer. The mask is clearly something magical that turns the poison into an antidote to the person wearing the mask.
In Zaire, as a kid, when they first found the Triffids (Bill, and his mum & dad), the natives performed a ritual on him which made him immune to the venom of the triffids, although he didn't know this at the time. It's clearly a special property of the mask.
Only now, that he has been stung again, and hence been hallucinating about the ritual with the masks since he was bandaged in the hospital, does he realise that the mask saved him, since it was used on him before.
And since the triffid poison is used in the ritual itself, if the ritual has been done afresh on all of them, they still have the poison/venom itself in their eyes, so, when the triffids look at them the triffids think that these people are already dead/poisoned. This is because the triffids kill this way, so when it sees poison in their eyes, they think that these people will die anyway, so they don't need to kill them twice, do they?
They effectively tricked the triffids into not killing them, and possible making themselves immune to their poison in the long run, like Bill was at the beginning of the tv series.
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