I think Penelope meant it in a way. As in, she just wanted it all to end, preferably with her being able to have a normal nose and a normal life, she's sick of being hidden away and offered for marriage and then rejected all the time. I think it just showed how desperate she was for "Max" to marry her because she saw him as her escape.
From Penelope's POV, "Max" would only ask what if the curse won't break because he is worried he'll be stuck with a pig-nosed wife, and doesn't want to agree to marry and change her. She doesn't want her chance at normalcy to disappear, so she tries this last-ditch attempt to assuage his fears.
From "Max"'s POV, he cares about Penelope and wants her to be happy, and based on her comment he believes that the only thing that would make her happy is lifting the curse. He believes she doesn't want *him*, she wants someone who will lift the curse, and since he knows he can't, he leaves.
If she'd answered any other way "Max" might have taken his chances and married her. And it also makes clear to the viewers that at that point in the movie, Penelope's main aim is escape, not love. It changes later.
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