No way!

I'm sorry, but there is no way that Zach Braff would catch the eye of someone as hot as Rachel Bilson at a wedding. He's got Mr. Potato Head lips and his nose looks like the goose from the original "Charlotte's Web" movie. There were many, many handsome guys at that wedding, someone who gets as much attention from men as she does never would have noticed him.

One other thing, I see the pregnant wife telling her dad, "only a little" when he pours a glass of champagne for her, but then later when Zach Braff is headed out to the party with Rachel Bilson, she is drinking a glass of wine.