Werner Herzog didn't need the ace of diamonds to beat Woody Harrelson
Werner could have won the hand also with Pocket 9s, Pockets 8s, or Pockets 6s for a full house, Pocket 2s for 4 of a kind, or 5&7 or 7&10 of diamonds for a straight flush.
Phil Gordon should have his commentator's license taken away. (...or at the very least, he should have told the director to change the community cards so a full house or straight flush weren't possible)
I'm actually a little disappointed by this.