What an odd question for Samantha to ask about organic vegetables.
In "The Real Me," the episode where Samantha is getting nudes pictures taken, she's worried about her figure and looking her best. So she asks the waitress if the vegetables on the veggie plate were organic. Why would she care about the vegetables being organic if she were just worried about her weight and figure? Organic and non-organic have the same amount of calorie and fat content. It's just non organic is sprayed with pesticides and preservatives, which are generally not healthy for you in the long run, but they don't cause weight gain.
Suprised Samantha does not know that.
My favorite New York moments:https://www.youtube.com/watch?v=MQ0Sqmnle6Y